Hydroxylamine Reactions with Peroxide Products of Alkenes Ozonolysis


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Reactions were studied of peroxide ozonolysis products obtained from linear and cyclic alkenes with hydroxylamine prepared in situ from NH2OH·HCl by hydrogen chloride neutralization with sodium acetate. A one-pot reactions sequence was performed: alkene oxidation with ozone → reduction to a carbonyl compound with hydroxylamine → condensation of the carbonyl compound with hydroxylamine providing a possibility of direct transformation of alkenes in keto- and aldoximes excluding the stage of preparation and isolation of the carbonyl compound.

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Yu. Legostaeva

Ufa Institute of Chemistry

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Email: legostaevayuv@yandex.ru
俄罗斯联邦, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

L. Garifullina

Ufa Institute of Chemistry

Email: legostaevayuv@yandex.ru
俄罗斯联邦, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

I. Nazarov

Ufa Institute of Chemistry

Email: legostaevayuv@yandex.ru
俄罗斯联邦, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

N. Ishmuratova

Ufa Institute of Chemistry

Email: legostaevayuv@yandex.ru
俄罗斯联邦, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

G. Ishmuratov

Ufa Institute of Chemistry

Email: legostaevayuv@yandex.ru
俄罗斯联邦, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054

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