Reaction of Lithium Acylate α-Carbanions with Carbon Tetrachloride
- 作者: Zorin A.V.1, Zaynashev A.T.1, Zorin V.V.1
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隶属关系:
- Ufa State Petroleum Technological University
- 期: 卷 55, 编号 1 (2019)
- 页面: 42-46
- 栏目: Article
- URL: https://journal-vniispk.ru/1070-4280/article/view/219706
- DOI: https://doi.org/10.1134/S1070428019010068
- ID: 219706
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详细
Metalation of acetic, butanoic, or 2-methylpropanoic acid with lithium diisopropylamide in tetrahydrofuran under argon gave the corresponding lithium acylate α-carbanions which reacted with carbon tetrachloride at 20–25°C for 2 h to afford butanedioic acid or its 2,3-diethyl and 2,2,3,3-tetramethyl derivatives, as well as the corresponding α-chlorocarboxylic acids and chloroform. A radical mechanism was proposed for the formation of dicarboxylic and α-chlorocarboxylic acids.
作者简介
A. Zorin
Ufa State Petroleum Technological University
编辑信件的主要联系方式.
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
A. Zaynashev
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
V. Zorin
Ufa State Petroleum Technological University
Email: chemist.518@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, Bashkortostan, 450062
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