Polyaromatic Products of Three-Component Coupling of Aryl Halide with Two Molecules of Arylacetylene and Arylboronic Acid under Ligand-Free Catalysis Conditions


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The aryl halide-arylacetylene-arylboronic acid three-component coupling in the presence of a Pd catalyst containing no organic ligands is described. The reaction routes that take place in the reaction system are shown to include the consecutive carbopalladation of two arylacetylene molecules, leading to unsaturated polyaromatic compounds. The possibility of controlling the alternative reaction routes is demonstrated.

作者简介

E. Yarosh

Irkutsk State University

Email: aschmidt@chem.isu.ru
俄罗斯联邦, ul. K. Marksa 1, Irkutsk, 664003

E. Larina

Irkutsk State University

Email: aschmidt@chem.isu.ru
俄罗斯联邦, ul. K. Marksa 1, Irkutsk, 664003

N. Lagoda

Irkutsk State University

Email: aschmidt@chem.isu.ru
俄罗斯联邦, ul. K. Marksa 1, Irkutsk, 664003

A. Kurokhtina

Irkutsk State University

Email: aschmidt@chem.isu.ru
俄罗斯联邦, ul. K. Marksa 1, Irkutsk, 664003

A. Schmidt

Irkutsk State University

编辑信件的主要联系方式.
Email: aschmidt@chem.isu.ru
俄罗斯联邦, ul. K. Marksa 1, Irkutsk, 664003

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