New Reaction of Dimethylformamide with Acrylic Acid


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A new homogeneous reaction of dimethylformamide (DMF) with acrylic acid was studied. The reaction afforded previously unknown 3-[2-carboxyethyl(dimethyl)azaniumyl]propanoate and carbon monoxide. The product structure was determined by 1H and 13C NMR spectroscopy, X-ray diffraction, and elemental analysis, and evolution of gaseous carbon monoxide was confirmed by GC/MS. The kinetic parameters of the described reaction and its overall order were determined.

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A. Akhmadullina

“AhmadullinS Science and Technologies”

编辑信件的主要联系方式.
Email: ahmadullins@gmail.com
俄罗斯联邦, Kazan, 420029

R. Akhmadullin

“AhmadullinS Science and Technologies”

Email: ahmadullins@gmail.com
俄罗斯联邦, Kazan, 420029

A. Gazizov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: ahmadullins@gmail.com
俄罗斯联邦, Kazan, 420088

A. Gubaidullin

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: ahmadullins@gmail.com
俄罗斯联邦, Kazan, 420088

A. Lisin

Kazan National Research Technological University

Email: ahmadullins@gmail.com
俄罗斯联邦, Kazan, 420015

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