Hydrogenation of Unsaturated Hydrocarbons on Platinum and Palladium Catalysts Encapsulated in Mesoporous Bakelites
- Authors: Boronoev M.P.1, Kulikov A.B.2, Subbotina E.S.1, Kulikov L.A.1, Egazar’yants S.V.1, Kardasheva Y.S.1, Maksimov A.L.1,2, Karakhanov E.A.1
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Affiliations:
- Lomonosov Moscow State University
- A. V. Topchiev Institute of Petrochemical Synthesis, RAS
- Issue: Vol 53, No 3 (2017)
- Pages: 318-332
- Section: Research
- URL: https://journal-vniispk.ru/0009-3092/article/view/234962
- DOI: https://doi.org/10.1007/s10553-017-0808-4
- ID: 234962
Cite item
Abstract
Syntheses are reported for catalysts derived from platinum and palladium nanoparticles supported on a mesoporous phenol formaldehyde polymer modified by an ionic liquid. These catalysts are used for the hydrogenation of unsaturated compounds, specifically, acyclic and cyclic isoprenoids: isoprene, 2,5 – dimethyl–2,4–hexadiene, limonene, α –terpinene, γ –terpinene, as well as phenylacetylene, transstilbene, and 1,4–diphenyl–1,3–butadiene. High activity was found for these catalysts in hydrogenation reactions. The palladium catalysts were more active than their platinum analogs. The products of complete hydrogenation predominate in the hydrogenation of isoprenoids on the palladium catalysts, while monoene products predominate in the reactions on platinum catalysts.
About the authors
M. P. Boronoev
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
A. B. Kulikov
A. V. Topchiev Institute of Petrochemical Synthesis, RAS
Author for correspondence.
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
E. S. Subbotina
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
L. A. Kulikov
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
S. V. Egazar’yants
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
Yu. S. Kardasheva
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
A. L. Maksimov
Lomonosov Moscow State University; A. V. Topchiev Institute of Petrochemical Synthesis, RAS
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow; Moscow
E. A. Karakhanov
Lomonosov Moscow State University
Email: kar@petrol.chem.msu.ru
Russian Federation, Moscow
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