The constancy of the concentration of an inhibitor preventing the ignition of gases
- Authors: Azatyan V.V.1, Balayan G.V.1, Prokopenko V.M.1, Chapysheva N.V.1
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Affiliations:
- Institute of Structural Macrokinetics and Problems of Materials Science
- Issue: Vol 466, No 2 (2016)
- Pages: 21-24
- Section: Chemistry
- URL: https://journal-vniispk.ru/0012-5008/article/view/153565
- DOI: https://doi.org/10.1134/S0012500816020014
- ID: 153565
Cite item
Abstract
Mechanisms of consumption of inhibitors in gas mixtures in different combustion modes—ignition prevention and suppression of flame propagation and detonation—have been revealed. It has been found that no more than a few hundredths of a percent of the initial reagents, including the inhibitor, are consumed for the prevention of ignition. In suppression of flame propagation and detonation, the inhibitor is consumed only in chain termination reactions. Oxygen is additionally consumed only in reactions with the products of incomplete oxidation of the inhibitor. The results have been interpreted in the framework of the theory of nonisothermal chain processes.
About the authors
V. V. Azatyan
Institute of Structural Macrokinetics and Problems of Materials Science
Author for correspondence.
Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
G. V. Balayan
Institute of Structural Macrokinetics and Problems of Materials Science
Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. M. Prokopenko
Institute of Structural Macrokinetics and Problems of Materials Science
Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
N. V. Chapysheva
Institute of Structural Macrokinetics and Problems of Materials Science
Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
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