A new method for the synthesis of metal complexes with trans-[B20H18]2– dianion
- Авторлар: Avdeeva V.V.1, Malinina E.A.1, Goeva L.V.1, Kuznetsov N.T.1
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Мекемелер:
- Kurnakov Institute of General and Inorganic Chemistry
- Шығарылым: Том 474, № 2 (2017)
- Беттер: 141-143
- Бөлім: Chemistry
- URL: https://journal-vniispk.ru/0012-5008/article/view/154015
- DOI: https://doi.org/10.1134/S0012500817060052
- ID: 154015
Дәйексөз келтіру
Аннотация
A new method has been proposed for the synthesis of transition metal complexes with the trans-[B20H18]2– dianion from complexes with the closo-decaborate anion [B10H10]2– without changing the cationic part of the complex. A cerium(IV) salt has been used as an oxidizing agent. Complexes [NiL3][trans-B20H18] (L = Bipy, Phen) have been identified by elemental analysis and IR spectroscopy.
Авторлар туралы
V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Хат алмасуға жауапты Автор.
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
E. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
L. Goeva
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
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