Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides


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Molybdenum dioxide (Mo2) synthesized through thermal decomposition of the [MoO2(i-C3H7NHO)2] complex and containing a nanosized fraction has been studied by MALDI-TOF. The composition of clusters of lower nonstoichiometric molybdenum oxide cations in the gas phase has been determined, and theoretical calculations of the thermodynamic stability and structure of the isomers of the most symmetric structures have been performed. Molecular orbitals of the cationic and neutral clusters Mo5O8 and Mo5O9 have been examined, and the aromaticity of the Mo-Mo bonds in metallacycles has been demonstrated.

作者简介

E. Il’in

Kurnakov Institute of General and Inorganic Chemistry

编辑信件的主要联系方式.
Email: eg_ilin@mail.ru
俄罗斯联邦, Moscow, 119991

A. Beirakhov

Kurnakov Institute of General and Inorganic Chemistry

Email: eg_ilin@mail.ru
俄罗斯联邦, Moscow, 119991

V. Yarzhemskii

Kurnakov Institute of General and Inorganic Chemistry

Email: eg_ilin@mail.ru
俄罗斯联邦, Moscow, 119991

A. Buryak

Frumkin Institute of Physical Institute and Electrochemistry

Email: eg_ilin@mail.ru
俄罗斯联邦, Moscow, 119071

A. Gekhman

Kurnakov Institute of General and Inorganic Chemistry

Email: eg_ilin@mail.ru
俄罗斯联邦, Moscow, 119991

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