Email this article Photostimulated oxidation of water catalyzed by a tetranuclear ruthenium complex with lithium countercations
- Authors: Dzhabieva Z.M.1, Tkachenko V.Y.1, Dzhabiev T.S.1
-
Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 51, No 3 (2017)
- Pages: 215-218
- Section: Photochemistry
- URL: https://journal-vniispk.ru/0018-1439/article/view/157188
- DOI: https://doi.org/10.1134/S0018143917030043
- ID: 157188
Cite item
Open Access
Access granted
Subscription Access
Abstract
Photostimulated oxidation of water by potassium persulfate in the presence of photosensitizer bpy3RuCl2 ∙ 6H2O and ruthenium catalyst Li10[{Ru4(μ-O)4(μ-OH)2(H2O)4} ∙ (γ-SiW10O36)2] ∙ 10H2O has been studied. It has been shown that the quantum yield of O2 (0.29) is much higher than the quantum yield in a similar photocatalytic system with rubidium countercations (0.09).
About the authors
Z. M. Dzhabieva
Institute of Problems of Chemical Physics
Email: timur@cat.icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. Yu. Tkachenko
Institute of Problems of Chemical Physics
Email: timur@cat.icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
T. S. Dzhabiev
Institute of Problems of Chemical Physics
Author for correspondence.
Email: timur@cat.icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
Supplementary files
