Radiation synthesis of tetrafluoroethylene telomers with functional hydroxyl and amino end groups in Freon 113


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Abstract

The kinetics of radiation telomerization of tetrafluoroethylene in Freon 113 with ethanol and ammonia additives have been studied by kinetic calorimetry. Tetrafluoroethylene telomers with terminal hydroxyl and amino groups have been obtained. The molecular structure, properties, and composition of the telomers have been investigated by IR spectroscopy, thermogravimetry, and elemental analysis.

About the authors

P. P. Kushch

Institute of Problems of Chemical Physics

Author for correspondence.
Email: kpp@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

G. A. Kichigina

Institute of Problems of Chemical Physics

Email: kpp@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

D. P. Kiryukhin

Institute of Problems of Chemical Physics

Email: kpp@icp.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

D. Ya. Barinov

All-Russia Research Institute of Aviation Materials

Email: kpp@icp.ac.ru
Russian Federation, Moscow, 105005

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