Email this article Chemiluminescent Method for Determination of Rate Constants for Reactions of Triplet Aromatic Nitrenes
- Authors: Shamukaev V.A.1, Chainikova E.M.1, Idrisova A.M.2, Safiullin R.L.1
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Affiliations:
- Ufa Institute of Chemistry
- Bashkir State Pedagogical University
- Issue: Vol 52, No 2 (2018)
- Pages: 123-130
- Section: Photonics
- URL: https://journal-vniispk.ru/0018-1439/article/view/157343
- DOI: https://doi.org/10.1134/S0018143918020133
- ID: 157343
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Abstract
It has been shown that the chemiluminescence accompanying the deoxygenation of nitrosobenzenes with triphenylphosphine can be used to measure the rate constants of reactions of the intermediates triplet nitrenes with the system components nitroso compounds and triphenylphosphine.
About the authors
V. A. Shamukaev
Ufa Institute of Chemistry
Author for correspondence.
Email: kinetic@anrb.ru
Russian Federation, Ufa, Bashkortostan, 450054
E. M. Chainikova
Ufa Institute of Chemistry
Email: kinetic@anrb.ru
Russian Federation, Ufa, Bashkortostan, 450054
A. M. Idrisova
Bashkir State Pedagogical University
Email: kinetic@anrb.ru
Russian Federation, Ufa, Bashkortostan, 450000
R. L. Safiullin
Ufa Institute of Chemistry
Email: kinetic@anrb.ru
Russian Federation, Ufa, Bashkortostan, 450054
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