Formation of Singlet Oxygen during Thermal Degradation of Hydrotrioxides of Triorganosilanes
- Авторы: Khalitova L.R.1, Grabovskii S.A.1, Kabal’nova N.N.1
-
Учреждения:
- Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
- Выпуск: Том 53, № 6 (2019)
- Страницы: 435-437
- Раздел: Photonics
- URL: https://journal-vniispk.ru/0018-1439/article/view/157774
- DOI: https://doi.org/10.1134/S0018143919060109
- ID: 157774
Цитировать
Аннотация
The yield of singlet oxygen (1O2) due to the degradation of triethylsilane, dimethylphenylsilane, triphenylsilane, and dimethyl(trimethylsiloxy)silane hydrotrioxides has been determined for the first time using the IR chemiluminescence technique. The most effective sources of singlet oxygen in this series are triphenylsilyl hydrotrioxide and dimethyl(trimethylsiloxy)silyl hydrotrioxide. The yield of 1O2 upon their degradation is 69 and 92%, respectively.
Ключевые слова
Об авторах
L. Khalitova
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: stas_g@anrb.ru
Россия, Ufa, 450054
S. Grabovskii
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: stas_g@anrb.ru
Россия, Ufa, 450054
N. Kabal’nova
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: stas_g@anrb.ru
Россия, Ufa, 450054
Дополнительные файлы
