Email this article Formation of Singlet Oxygen during Thermal Degradation of Hydrotrioxides of Triorganosilanes
- Authors: Khalitova L.R.1, Grabovskii S.A.1, Kabal’nova N.N.1
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Affiliations:
- Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
- Issue: Vol 53, No 6 (2019)
- Pages: 435-437
- Section: Photonics
- URL: https://journal-vniispk.ru/0018-1439/article/view/157774
- DOI: https://doi.org/10.1134/S0018143919060109
- ID: 157774
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Abstract
The yield of singlet oxygen (1O2) due to the degradation of triethylsilane, dimethylphenylsilane, triphenylsilane, and dimethyl(trimethylsiloxy)silane hydrotrioxides has been determined for the first time using the IR chemiluminescence technique. The most effective sources of singlet oxygen in this series are triphenylsilyl hydrotrioxide and dimethyl(trimethylsiloxy)silyl hydrotrioxide. The yield of 1O2 upon their degradation is 69 and 92%, respectively.
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About the authors
L. R. Khalitova
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: stas_g@anrb.ru
Russian Federation, Ufa, 450054
S. A. Grabovskii
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Author for correspondence.
Email: stas_g@anrb.ru
Russian Federation, Ufa, 450054
N. N. Kabal’nova
Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of Sciences
Email: stas_g@anrb.ru
Russian Federation, Ufa, 450054
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