Email this article Applications of nuclear magnetic resonance to study the structure of platinum-group metal complexes in aqueous solutions
- Authors: Fedotov M.A.1
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Affiliations:
- Boreskov Institute of Catalysis, Siberian Branch
- Issue: Vol 57, No 3 (2016)
- Pages: 563-613
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/159801
- DOI: https://doi.org/10.1134/S0022476616030203
- ID: 159801
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Abstract
The review includes comprehensive NMR data on platinum metals (99,101Ru, 103Rh, 105Pd, 187Os, 195Pt) and ligand donor atoms (1H, 13C, 14,15N, 17O, 19F, 31P) of metal complexes in aqueous solutions. A systematic analysis of NMR spectroscopy techniques is presented with focus on the measurements of NMR parameters in these systems. A novel concept referred to as coordinate shift is introduced, allowing interpretation of NMR spectra of platinum metal complexes. The review contains an encyclopedic NMR database covering a period of over 50 years from the first measured NMR spectra of platinum metals to 2014.
About the authors
M. A. Fedotov
Boreskov Institute of Catalysis, Siberian Branch
Author for correspondence.
Email: olga@catalysis.ru
Russian Federation, Novosibirsk
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