Email this article Crystallochemical study of ruthenium(III) tris-dipivaloylmethanate
- Authors: Sysoev S.V.1,2, Naumov D.Y.1,3, Kuratieva N.V.1,3, Zherikova K.V.1, Gromilov S.A.1,3, Morozova N.B.1, Kuzin T.M.1, Gelfond N.V.1
-
Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University of Architecture and Civil Engineering
- Novosibirsk National Research State University
- Issue: Vol 57, No 4 (2016)
- Pages: 826-829
- Section: Brief Communications
- URL: https://journal-vniispk.ru/0022-4766/article/view/160098
- DOI: https://doi.org/10.1134/S0022476616040314
- ID: 160098
Cite item
Open Access
Access granted
Subscription Access
Abstract
The structure of ruthenium(III) dipivaloylmethanate is determined by single crystal X-ray diffraction at temperature of 150 K. The crystallographic data for C33H57O6Ru are as follows: a = 9.6119(11) Å, b = 17.4603(19) Å, c = 21.519(2) Å, β = 95.187(2)°, C2/c space group, V = 3596.7(7) Å3, Z = 4, dcalc = = 1.202 g/cm3, R = 0.0642. The structure is molecular, the metal atom coordinates six oxygen atoms of three ligands of β-diketone. The Ru–O distances are in the range of 1.99 Å to2.03 Å. The complexes have a distorted single layer hexagonal packing with the Ru…Ru distances being 9.84 Å within the layer, and 10.93 Å between the layers.
About the authors
S. V. Sysoev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University of Architecture and Civil Engineering
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
D. Yu. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
K. V. Zherikova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk
S. A. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
N. B. Morozova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk
T. M. Kuzin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Gelfond
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: kuzin@niic.nsc.ru
Russian Federation, Novosibirsk
Supplementary files
