Email this article A quantum chemical NMR study of branched and unbranched fluoropolymers
- Authors: Ignatieva L.N.1, Bouznik V.M.2
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Affiliations:
- Institute of Chemistry, Far East Branch
- All-Russian Scientific Research Institute of Aviation Materials
- Issue: Vol 57, No 5 (2016)
- Pages: 892-900
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/160156
- DOI: https://doi.org/10.1134/S0022476616050073
- ID: 160156
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Abstract
The work demonstrates the results of quantum chemical calculations of 19F and 13C NMR spectra of model fluorocarbon CnF2n+2 molecules with various configurations and hydrocarbon chain molecules. The possibilities to determine the chain length, formation of branches, identification of fluorine substitution for hydrogen during the fluorination of hydrocarbon paraffins and polymers are discussed.
About the authors
L. N. Ignatieva
Institute of Chemistry, Far East Branch
Author for correspondence.
Email: ignatieva@ich.dvo.ru
Russian Federation, Vladivostok
V. M. Bouznik
All-Russian Scientific Research Institute of Aviation Materials
Email: ignatieva@ich.dvo.ru
Russian Federation, Moscow
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