Email this article Structure and location of proton hydrates in Triton N-42 reverse micelles during injection solubilization of HCl solutions
- Authors: Podlipskaya T.Y.1, Bulavchenko A.I.1
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 57, No 8 (2016)
- Pages: 1561-1567
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/160383
- DOI: https://doi.org/10.1134/S0022476616080102
- ID: 160383
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Abstract
A Fourier IR spectroscopic study has shown that during injection solubilization* of HCl solutions (Vs/Vo = 1.0-3.5 vol.%) at a concentration of 1-4 M by Triton N-42 reverse micelles in n-decane, the number of water molecules bound to protons is equal to 2.7±0.1. Protons form H7O3+ (70%) and H5O2+ (30%) cations in equilibrium, which are localized in the aqueous cores of the micelles.
About the authors
T. Yu. Podlipskaya
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: tatyanap@niic.nsc.ru
Russian Federation, Novosibirsk
A. I. Bulavchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: tatyanap@niic.nsc.ru
Russian Federation, Novosibirsk
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