Compressibility, phase transitions and amorphization of coronene at pressures up to 6 GPa


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Abstract

The work is devoted to the experimental study of coronene C24H12 at high pressure and room temperature using in situ X-ray diffraction in a diamond anvil cell. The high-pressure phase P2/m of coronene was found at 0.9 GPa, the PV-equation of state for P2/m coronene phase was defined to 4 GPa: K0 = 10.8(3) GPa, K0 = 7. At 5.9 GPa partial amorphization of coronene was observed. After the decompression to ambient pressure the high-pressure phase P2/m was preserved, that can be related with partial amorphization.

About the authors

A. D. Chanyshev

Sobolev Institute of Geology and Mineralogy, Siberian Branch; Novosibirsk National Research State University

Author for correspondence.
Email: chanyshev_90@mail.ru
Russian Federation, Novosibirsk; Novosibirsk

A. Yu. Likhacheva

Sobolev Institute of Geology and Mineralogy, Siberian Branch; Budker Institute of Nuclear Physics, Siberian Branch

Email: chanyshev_90@mail.ru
Russian Federation, Novosibirsk; Novosibirsk

P. N. Gavryushkin

Sobolev Institute of Geology and Mineralogy, Siberian Branch; Novosibirsk National Research State University

Email: chanyshev_90@mail.ru
Russian Federation, Novosibirsk; Novosibirsk

K. D. Litasov

Sobolev Institute of Geology and Mineralogy, Siberian Branch; Novosibirsk National Research State University

Email: chanyshev_90@mail.ru
Russian Federation, Novosibirsk; Novosibirsk

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