Email this article Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts
- Authors: Vasilchenko D.B.1,2, Semitut E.Y.1,3, Bykova E.A.4, Korenev S.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- National Research Tomsk Polytechnic University
- Bavarian Research Institute of Experimental Geochemistry and Geophysics
- Issue: Vol 58, No 1 (2017)
- Pages: 84-89
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161040
- DOI: https://doi.org/10.1134/S0022476617010127
- ID: 161040
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Abstract
New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.
About the authors
D. B. Vasilchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: semitut@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
E. Yu. Semitut
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; National Research Tomsk Polytechnic University
Author for correspondence.
Email: semitut@niic.nsc.ru
Russian Federation, Novosibirsk; Tomsk
E. A. Bykova
Bavarian Research Institute of Experimental Geochemistry and Geophysics
Email: semitut@niic.nsc.ru
Germany, Bayreuth
S. V. Korenev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: semitut@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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