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Molecular and crystal structure of a cationic dinitrosyl iron complex with 1,3-dimethylthiourea


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Abstract

A new dinitrosyl iron complex of the composition [Fe(SC(NHCH3)2)2(NO)2]Cl (I) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic features of the molecular and crystal structure of complex I is determined by single crystal X-ray diffraction analysis.

About the authors

N. Yu. Shmatko

Institute of Problems of Chemical Physics

Author for correspondence.
Email: natashashmatko@gmail.com
Russian Federation, Chernogolovka

D. V. Korchagin

Institute of Problems of Chemical Physics

Email: natashashmatko@gmail.com
Russian Federation, Chernogolovka

G. V. Shilov

Institute of Problems of Chemical Physics

Email: natashashmatko@gmail.com
Russian Federation, Chernogolovka

N. A. Sanina

Institute of Problems of Chemical Physics

Email: natashashmatko@gmail.com
Russian Federation, Chernogolovka

S. M. Aldoshin

Institute of Problems of Chemical Physics

Email: natashashmatko@gmail.com
Russian Federation, Chernogolovka

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