Email this article Crystal structure of binuclear bismuth complexes [H2dabco]2[Bi2Cl10]·2H2O and (H3O)2[H2dabco]4[Bi2Br10][BiBr6]2·4.5H2O
- Authors: Kovalenko E.A.1, Kochelakov D.V.1,2, Samsonenko D.G.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 58, No 3 (2017)
- Pages: 591-596
- Section: Brief Communications
- URL: https://journal-vniispk.ru/0022-4766/article/view/161315
- DOI: https://doi.org/10.1134/S0022476617030210
- ID: 161315
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Abstract
Binuclear bismuth complexes [H2dabco]2[Bi2Cl10]·2H2O and (H3O)2[H2dabco]4[Bi2Br10][BiBr6]2·4.5H2O are obtained by heating (100 °C) acidic solutions of a mixture of bismuth chloride and bromide with dabco. The structure of the complexes is determined by single crystal X-ray diffraction.
About the authors
E. A. Kovalenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk
D. V. Kochelakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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