Email this article Structure of a trinuclear μ3-vinylidene cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6
- Authors: Chudin O.S.1, Verpekin V.V.1, Vasiliev A.D.2,3,4, Rubaylo A.I.1,3,4
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Affiliations:
- Institute of Chemistry and Chemical Technology, Siberian Branch
- Kirensky Institute of Physics, Siberian Branch
- Krasnoyarsk Scientific Center, Siberian Branch
- Siberian Federal University
- Issue: Vol 58, No 3 (2017)
- Pages: 600-602
- Section: Brief Communications
- URL: https://journal-vniispk.ru/0022-4766/article/view/161321
- DOI: https://doi.org/10.1134/S0022476617030234
- ID: 161321
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Abstract
The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ3-C=CHPh)(PPh3)(CO)6 is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å3, space group C2/c, Z = 8, dcalc = 1.741 g/cm3. The cluster molecule contains a bridging phenylvinylidene ligand coordinated to a metallic core in the form of a Mn–Fe–Pt chain (the Mn–Fe and Fe–Pt bond lengths are 2.6768(14) Å and 2.6280(11) Å respectively and the Mn⋯Pt distance is 3.6425(19) Å).
About the authors
O. S. Chudin
Institute of Chemistry and Chemical Technology, Siberian Branch
Author for correspondence.
Email: oschudin@mail.ru
Russian Federation, Krasnoyarsk
V. V. Verpekin
Institute of Chemistry and Chemical Technology, Siberian Branch
Email: oschudin@mail.ru
Russian Federation, Krasnoyarsk
A. D. Vasiliev
Kirensky Institute of Physics, Siberian Branch; Krasnoyarsk Scientific Center, Siberian Branch; Siberian Federal University
Email: oschudin@mail.ru
Russian Federation, Krasnoyarsk; Krasnoyarsk; Krasnoyarsk
A. I. Rubaylo
Institute of Chemistry and Chemical Technology, Siberian Branch; Krasnoyarsk Scientific Center, Siberian Branch; Siberian Federal University
Email: oschudin@mail.ru
Russian Federation, Krasnoyarsk; Krasnoyarsk; Krasnoyarsk
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