Crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate

Yu. I. Bolgova; T. N. Borodina; O. M. Trofimova; V. I. Smirnov

doi:10.1134/S002247661703026X

Crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate

Authors: Bolgova Y.I.¹, Borodina T.N.¹, Trofimova O.M.¹, Smirnov V.I.¹
Affiliations:
1. Favorsky Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 58, No 3 (2017)
Pages: 611-614
Section: Brief Communications
URL: https://journal-vniispk.ru/0022-4766/article/view/161334
DOI: https://doi.org/10.1134/S002247661703026X
ID: 161334

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Abstract

The XRD method is used to determine the molecular and crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate (H₂C=C(Me)C(O)OCH₂Si(OCH₂CH₂)₃N). The crystallographic data are as follows: space group Р2₁2₁2₁, а = 9.7659(1) Å, b = 10.017(1) Å, с = 17.915(2) Å, V = 1753.3(3) Å³, Z = 4. The coordination polyhedron of the silicon atom is a distorted trigonal bipyramid. The length of the N→Si coordination bond is 2.099 Å.