Structure of a new chelate complex MO 2 O 3 (dpm) 4

A. Yu. Ledneva; S. B. Artemkina; P. A. Stabnikov; L. V. Yanshole; V. E. Fedorov

doi:10.1134/S0022476617040163

Structure of a new chelate complex MO₂O₃(dpm)₄

Authors: Ledneva A.Y.¹, Artemkina S.B.¹, Stabnikov P.A.¹, Yanshole L.V.², Fedorov V.E.¹
Affiliations:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
2. International Tomography Center, Siberian Branch
Issue: Vol 58, No 4 (2017)
Pages: 758-762
Section: Article
URL: https://journal-vniispk.ru/0022-4766/article/view/161420
DOI: https://doi.org/10.1134/S0022476617040163
ID: 161420

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Abstract

A new Mo₂O₃(dpm)₄ compound (I) is synthesized by the interaction of Mo(CO)₆ with 2,2,6,6-tetramethylheptanedione-3,5 (dpm). The structure of complex I determined by the XRD method is as follows: triclinic crystal system, space group P–1, a = 10.1780(7) Å, b = 10.1817(6) Å, c = 13.3255(9) Å, α = 110.562(2)°, β = 102.233(2)°, γ = 93.9041(19)°, V = 1248.17(14) Å³. The compound is characterized by IR spectroscopy, mass-spectrometry and thermogravimetric analysis (TGA).