Email this article Structural characterization of a bioctahedral cluster [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– anion
- Authors: Lappi T.I.1, Gayfulin Y.M.2, Smolentsev A.I.1,2, Mironov Y.V.1,2
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Affiliations:
- Novosibirsk National Research State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 58, No 4 (2017)
- Pages: 835-837
- Section: Brief Communications
- URL: https://journal-vniispk.ru/0022-4766/article/view/161460
- DOI: https://doi.org/10.1134/S002247661704031X
- ID: 161460
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Abstract
The [Zn(H2O)4]3[Re12CS14(μ-SO2)(μ-S)2(CN)6]0.875[Re12CS14(μ-S)3(CN)6]0.125•6H2O compound (1) containing a new [Re12CS14(μ-SO2)(μ-S)2(CN)6]6– cluster anion is synthesized by the reaction of ZnCl2 and K6[Re12CS14(μ-S/SO/SO2)3(CN)6] in an aqueous solution and structurally characterized. Compound 1 crystallizes in a rhombic space group Pnma with the following unit cell parameters: a = 22.0834(7) Å, b = 28.2551(9) Å, c = 9.7775(3) Å, V = 6100.9(3) Å3, Z = 4, dcalc = 3.806 g/cm3. The crystal structure consists of two cluster anions in the ratio 7:1, occupying the same position, distorted [Zn(H2O)4]2+ cations, and solvate H2O molecules linked by hydrogen bonds.
About the authors
T. I. Lappi
Novosibirsk National Research State University
Email: gayfulin@niic.nsc.ru
Russian Federation, Novosibirsk
Ya. M. Gayfulin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: gayfulin@niic.nsc.ru
Russian Federation, Novosibirsk
A. I. Smolentsev
Novosibirsk National Research State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gayfulin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
Yu. V. Mironov
Novosibirsk National Research State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gayfulin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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