Email this article In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]
- Authors: Asanova T.I.1, Asanov I.P.1,2, Kim M.3, Korenev S.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry Siberian Branch
- Novosibirsk National Research University
- Beamline Research Division
- Issue: Vol 58, No 5 (2017)
- Pages: 901-910
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161485
- DOI: https://doi.org/10.1134/S0022476617050079
- ID: 161485
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Abstract
In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH3)4][OsCl6] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.
About the authors
T. I. Asanova
Nikolaev Institute of Inorganic Chemistry Siberian Branch
Author for correspondence.
Email: nti@niic.nsc.ru
Russian Federation, Novosibirsk
I. P. Asanov
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University
Email: nti@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
M.-G. Kim
Beamline Research Division
Email: nti@niic.nsc.ru
Korea, Republic of, Pohang
S. V. Korenev
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University
Email: nti@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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