Email this article Crystal structure and EPR spectra of (Bu4N)2[V(dmit)3]
- Authors: Fomenko Y.S.1, Gushchin A.L.1,2, Nadolinny V.A.1, Abramov P.A.1, Sokolov M.N.1,2
-
Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 58, No 5 (2017)
- Pages: 964-969
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161503
- DOI: https://doi.org/10.1134/S0022476617050158
- ID: 161503
Cite item
Open Access
Access granted
Subscription Access
Abstract
The tris-chelate complex of vanadium(IV) (Bu4N)2[V(dmit)3] is prepared from VCl3 and (Bu4N)2[Zn(dmit)2] (dmit = isotrithionedithiolate C3S52–) and characterized by single crystal XRD and mass spectrometry. The complex crystallizes in the space group Pna21 and has a distorted octahedral environment of vanadium. The complex is paramagnetic and gives a characteristic EPR spectrum in both solution and solid phase. The g factors and hyperfine interaction constants are determined.
Keywords
About the authors
Ya. S. Fomenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk
A. L. Gushchin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
V. A. Nadolinny
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: gushchin@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
Supplementary files
