Email this article Lithium carboxylate coordination polymers based on trimesic acid
- Authors: Koltunova T.K.1, Samsonenko D.G.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 58, No 5 (2017)
- Pages: 1048-1055
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161538
- DOI: https://doi.org/10.1134/S0022476617050274
- ID: 161538
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Abstract
Three new metal-organic coordination polymers (H2NMe2)2[Li3(btc)(Hbtc)(DMF)4] (1), [Li5(DMF)6(btc)(Hbtc)]·2DMF (2), and [Li6(DMF)8(bdc)(Hbtc)] (3) (H3btc is trimesic acid, H2bdc is terephthalic acid) are prepared by heating LiOH with different aromatic carboxylic acids in dimethyl formamide (or its mixture with water). The crystal structures and composition of the compounds are determined by single crystal X-ray diffraction. Compound 1 has a layered structure; compounds 2 and 3 have a framework structure.
About the authors
T. K. Koltunova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk
D. G. Samsonenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
D. N. Dybtsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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