Crystal structure of the (N,N′-bis[chromen-2,4-dione]-3-{2′-hydroxypropylenediamine-N,N′,O,O′}) (dimethylsulfoxide)copper(II) complex

L. D. Popov; I. N. Shcherbakov; V. G. Vlasenko; S. I. Levchenkov; G. G. Aleksandrov

doi:10.1134/S0022476617070228

Crystal structure of the (N,N′-bis[chromen-2,4-dione]-3-{2′-hydroxypropylenediamine-N,N′,O,O′}) (dimethylsulfoxide)copper(II) complex

Authors: Popov L.D.¹, Shcherbakov I.N.¹, Vlasenko V.G.², Levchenkov S.I.¹^,3, Aleksandrov G.G.⁴
Affiliations:
1. Southern Federal University
2. Research Institute of Physics of the Southern Federal University
3. Southern Scientific Center
4. Kurnakov Institute of General and Inorganic Chemistry
Issue: Vol 58, No 7 (2017)
Pages: 1432-1435
Section: Article
URL: https://journal-vniispk.ru/0022-4766/article/view/161649
DOI: https://doi.org/10.1134/S0022476617070228
ID: 161649

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Abstract

The N,N′-bis[chromen-2,4-dione]-3-{2′-hydroxypropylenediamine-N,N′,O,O′}copper(II) solvate complex with dimethylsulfoxide is synthesized. The crystal and molecular structure of the complex is determined by X-ray diffraction. The coordination polyhedron of the copper atom is a square pyramid with the base formed by two oxygen atoms and two nitrogen atoms of the ligand and a vertex consisting of the oxygen atom of the coordinated DMSO molecule.