Email this article Structure of a product of free radical substitution of a chlorine atom for 1,3,5-trioxane in an iron(II) chlathrochelate
- Authors: Vershinin M.A.1, Burdukov A.B.1, Pervukhina N.V.1, Kuratieva N.V.1, Eltsov I.V.2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Issue: Vol 58, No 8 (2017)
- Pages: 1672-1675
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161723
- DOI: https://doi.org/10.1134/S0022476617080273
- ID: 161723
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Abstract
A tert-BuOOH/Fe(II) system is used for the free radical substitution of the chlorine atom at the rib of a boron capped iron(II) tris-dioximate chlathrochelate for 1,3,5-trioxane. The structure of the compound is determined by single crystal XRD and solution NMR.
About the authors
M. A. Vershinin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: lscc@niic.nsc.ru
Russian Federation, Novosibirsk
A. B. Burdukov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: lscc@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: lscc@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: lscc@niic.nsc.ru
Russian Federation, Novosibirsk
I. V. Eltsov
Novosibirsk National Research State University
Email: lscc@niic.nsc.ru
Russian Federation, Novosibirsk
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