Email this article Structural Features And Properties of Heteronuclear Germanium(IV) and Some 3d Metal Complexes with Xylaric Acid and 2,2′-Bipyridine
- Authors: Chebanenko E.A.1, Martsinko E.E.1, Seifullina I.I.1, Dyakonenko V.V.2, Shishkina S.V.2,3
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Affiliations:
- Mechnikov Odessa National University
- Scientific Technological Complex “Institute for Single Crystals”
- Karazin Kharkov National University
- Issue: Vol 59, No 6 (2018)
- Pages: 1462-1468
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161751
- DOI: https://doi.org/10.1134/S0022476618060318
- ID: 161751
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Abstract
New coordination compounds of germanium and 3d metals with xylaric acid (H5Xylar) and 2,2′-bipyridine (bipy), which contain tetranuclear xylaratogermanate anion [Fe(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ- OH)2]·12Н2О·2CH3CN (I) and [Ni(bipy)3]2[(OH)2Ge2(μ-HXylar)4Ge2(μ-OH)2]·20Н2О·2C2H5OH (II) are synthesized. The complexes are studied by the elemental analysis, thermogravimetry, IR spectroscopy, and X-ray diffraction. To visualize and quantitatively assess hydrogen bonds in I and II the Hiershfeld surface analysis is used.
About the authors
E. A. Chebanenko
Mechnikov Odessa National University
Author for correspondence.
Email: lborn@ukr.net
Ukraine, Odesa
E. E. Martsinko
Mechnikov Odessa National University
Email: lborn@ukr.net
Ukraine, Odesa
I. I. Seifullina
Mechnikov Odessa National University
Email: lborn@ukr.net
Ukraine, Odesa
V. V. Dyakonenko
Scientific Technological Complex “Institute for Single Crystals”
Email: lborn@ukr.net
Ukraine, Kharkov
S. V. Shishkina
Scientific Technological Complex “Institute for Single Crystals”; Karazin Kharkov National University
Email: lborn@ukr.net
Ukraine, Kharkov; Kharkov
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