Отправить статью по E-mail Synthesis Characterization, Crystal Structure, and Fluorescence of a New Samarium Schiff Base Complex
- Авторы: Abu-Yamin A.A.1, AlDamen M.A.2, Sinnokrot M.O.3, Juwhari H.K.4, Salman M.1, Sarairah I.1, Al-Hawarin J.1, Mubarak M.S.2
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Учреждения:
- Department of Chemistry, Faculty of Science
- School of Chemistry
- Department of Chemistry, College of Arts and Sciences
- School of Physics
- Выпуск: Том 59, № 8 (2018)
- Страницы: 1935-1943
- Раздел: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161814
- DOI: https://doi.org/10.1134/S0022476618080243
- ID: 161814
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Аннотация
A new samarium Schiff base complex with the formula [SmIII(NO3)3(H2O)L2].EtOH, where L = {(E)-2- (((4-(ethoxycarbonyl)phenyl)iminio)-methyl)phenolate}, is synthesized. Its molecular structure is determined by means of single crystal X-ray diffraction (XRD). The complex crystallizes in the orthorhombic space group Pbca with the following unit cell dimensions: a = 14.1304(19) Å, b = 18.0218(13) Å, and c = 31.246(2) Å. Photoluminescence characteristics of the complex are investigated experimentally in the solid state and obtained theoretically using the Sparkle/PM7 modeling. Moreover, several methods such as powder XRD, FT-IR and UV-Visible spectroscopy are utilized to confirm the structure of the complex.
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Об авторах
A. Abu-Yamin
Department of Chemistry, Faculty of Science
Email: maldamen@ju.edu.jo
Иордания, Ma’an
M. AlDamen
School of Chemistry
Автор, ответственный за переписку.
Email: maldamen@ju.edu.jo
Иордания, Amman
M. Sinnokrot
Department of Chemistry, College of Arts and Sciences
Email: maldamen@ju.edu.jo
ОАЭ, Abu Dhabi
H. Juwhari
School of Physics
Email: maldamen@ju.edu.jo
Иордания, Amman
M. Salman
Department of Chemistry, Faculty of Science
Email: maldamen@ju.edu.jo
Иордания, Ma’an
I. Sarairah
Department of Chemistry, Faculty of Science
Email: maldamen@ju.edu.jo
Иордания, Ma’an
J. Al-Hawarin
Department of Chemistry, Faculty of Science
Email: maldamen@ju.edu.jo
Иордания, Ma’an
M. Mubarak
School of Chemistry
Email: maldamen@ju.edu.jo
Иордания, Amman
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