Email this article Crystal Structure of Binuclear Cobalt Complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] and [(Cp′′′Co)2(μ2-η1:η2-Se2)2]
- Authors: Afonin M.Y.1, Sukhikh T.S.1,2, Konchenko S.N.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 1 (2018)
- Pages: 136-139
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161846
- DOI: https://doi.org/10.1134/S0022476618010201
- ID: 161846
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Abstract
Binuclear cobalt complexes [(Cp′′′Co)2(μ2-η1:η2-S2)2] (1) (Cp′′′ = η5-1,2,4-tris(tert-butyl)cyclopentadienide) and [(Cp′′′Co)2(μ2-η1:η2-Se2)2] (2) are obtained by the interaction of [(Cp′′′Co)2(μ-η4:η4-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.
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About the authors
M. Yu. Afonin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: snkonch@niic.nsc.ru
Russian Federation, Novosibirsk
T. S. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: snkonch@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. N. Konchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: snkonch@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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