Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex
- Authors: Tkachev V.V.1, Utenyshev A.N.1,2, Chernyshov A.I.3, Kovalchukova O.V.4
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Affiliations:
- Institute of Problems of Chemical Physics
- Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation
- Institute of Physical and Organic Chemistry
- Peoples’ Friendship University of Russia
- Issue: Vol 59, No 2 (2018)
- Pages: 425-428
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161889
- DOI: https://doi.org/10.1134/S0022476618020245
- ID: 161889
Cite item
Abstract
X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom.
About the authors
V. V. Tkachev
Institute of Problems of Chemical Physics
Author for correspondence.
Email: vatka@icp.ac.ru
Russian Federation, Chernogolovka, Moscow Region
A. N. Utenyshev
Institute of Problems of Chemical Physics; Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation
Email: vatka@icp.ac.ru
Russian Federation, Chernogolovka, Moscow Region; Moscow
A. I. Chernyshov
Institute of Physical and Organic Chemistry
Email: vatka@icp.ac.ru
Russian Federation, Rostov-on-Don
O. V. Kovalchukova
Peoples’ Friendship University of Russia
Email: vatka@icp.ac.ru
Russian Federation, Moscow
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