Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex


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Abstract

X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a transtranscis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom.

About the authors

V. V. Tkachev

Institute of Problems of Chemical Physics

Author for correspondence.
Email: vatka@icp.ac.ru
Russian Federation, Chernogolovka, Moscow Region

A. N. Utenyshev

Institute of Problems of Chemical Physics; Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation

Email: vatka@icp.ac.ru
Russian Federation, Chernogolovka, Moscow Region; Moscow

A. I. Chernyshov

Institute of Physical and Organic Chemistry

Email: vatka@icp.ac.ru
Russian Federation, Rostov-on-Don

O. V. Kovalchukova

Peoples’ Friendship University of Russia

Email: vatka@icp.ac.ru
Russian Federation, Moscow

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