Email this article Crystal Structures of Ru(II) Complexes with Pyrazole and Pyrazolate Derivatives of tris(3,5-Dimethylpyrazolyl)Borohydride
- Authors: Kharbani D.1, Kurbah S.D.1, Rymmai E.K.1
-
Affiliations:
- Centre for Advanced Studies in Chemistry
- Issue: Vol 59, No 5 (2018)
- Pages: 1186-1191
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/161999
- DOI: https://doi.org/10.1134/S0022476618050232
- ID: 161999
Cite item
Open Access
Access granted
Subscription Access
Abstract
Mononuclear cis,cis,trans-[Ru(CO)2Cl2(Pz*H)2] (1) and dinuclear [Ru2(DMSO)3Cl2(Pz*H)× (μ-H)(μ-Pz*)(μ-DMSO)] (2) complexes (DMSO = dimethylsulfoxide and Pz* = 3,5-dimethylpyrazolate) are obtained by the reaction of KTp* in methanol (KTp* = potassium tris(3,5-dimethylpyrazolyl)borate) with [Ru(CO)3Cl2]2 and cis-[RuCl2(DMSO)4] precursors, respectively. These complexes are obtained from the degradation of the scorpionate KTp* ligand and characterized by IR, 1H NMR, and X-ray crystallography.
Keywords
About the authors
D. Kharbani
Centre for Advanced Studies in Chemistry
Email: ekrymmai68@gmail.com
India, Shillong, Meghalaya
S. D. Kurbah
Centre for Advanced Studies in Chemistry
Email: ekrymmai68@gmail.com
India, Shillong, Meghalaya
E. K. Rymmai
Centre for Advanced Studies in Chemistry
Author for correspondence.
Email: ekrymmai68@gmail.com
India, Shillong, Meghalaya
Supplementary files
