Email this article Crystal Structure and DFT Study of N-(6-(Diphenylamino)Pyridin-2-Yl)-N-Phenylacetamide
- Authors: Okuda T.1, Umezono S.1, Okuno T.1
-
Affiliations:
- Department of Materials Science and Chemistry
- Issue: Vol 60, No 3 (2019)
- Pages: 394-397
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/162071
- DOI: https://doi.org/10.1134/S0022476619030065
- ID: 162071
Cite item
Open Access
Access granted
Subscription Access
Abstract
The title compound N-(6-(diphenylamino)pyridin-2-yl)-N-phenylacetamide (1) crystallizes in the monoclinic crystal system in the space group P21/n with unit cell parameters a = 9.571(7) Å, b = 9.333(6) Å, c = 22.431(16) Å, β = 100.669(10)°, V = 1969(2) Å3, and Z = 4. The structures of amine and amide units are planar. Dihedral angles of a pyridine ring with the amine and amide planes are 20.19(11)° and 37.21(8)°, respectively, indicating that an electron-rich diphenylamino group makes better conjugation with an electron-deficient pyridine ring. The oxygen atom of the amide group forms an intramolecular hydrogen bond with a hydrogen atom of the pyridine ring.
About the authors
T. Okuda
Department of Materials Science and Chemistry
Email: okuno@center.wakayama-u.ac.jp
Japan, Sakaedani, Wakayama
S. Umezono
Department of Materials Science and Chemistry
Email: okuno@center.wakayama-u.ac.jp
Japan, Sakaedani, Wakayama
T. Okuno
Department of Materials Science and Chemistry
Author for correspondence.
Email: okuno@center.wakayama-u.ac.jp
Japan, Sakaedani, Wakayama
Supplementary files
