Email this article New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure
- Authors: Konokhova A.Y.1,2, Afonin M.Y.1, Sukhikh T.S.1,2, Konchenko S.N.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 60, No 9 (2019)
- Pages: 1463-1467
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/162187
- DOI: https://doi.org/10.1134/S0022476619090105
- ID: 162187
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Abstract
Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction.
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About the authors
A. Yu. Konokhova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: konch@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
M. Yu. Afonin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: konch@niic.nsc.ru
Russian Federation, Novosibirsk
T. S. Sukhikh
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: konch@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. N. Konchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Author for correspondence.
Email: konch@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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