Email this article Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)
- Authors: Adonin S.A.1,2,3,4, Sokolov M.N.1,2,5, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Tobolsk Industrial Institute
- Southern Ural State University
- Novosibirsk State University
- Butlerov Institute of Chemistry
- Issue: Vol 60, No 10 (2019)
- Pages: 1655-1659
- Section: Article
- URL: https://journal-vniispk.ru/0022-4766/article/view/162207
- DOI: https://doi.org/10.1134/S0022476619100111
- ID: 162207
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Abstract
By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.
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About the authors
S. A. Adonin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Tobolsk Industrial Institute; Southern Ural State University; Novosibirsk State University
Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Tobolsk; Chelyabinsk; Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Tobolsk Industrial Institute; Butlerov Institute of Chemistry
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Tobolsk; Kazan
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Tobolsk Industrial Institute
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk; Tobolsk
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