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Structure of Two Complexes of N-Thiophosphorylated Thioamides with a Silver(I) Cation and Triphenylphosphine


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Abstract

In order to study the complexation properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S)NHP(S)(OPri)2 (R = AlkNH, Alk2N, ArNH, PyNH, Ph, PhNHNH, NH2(Et)N) towards copper(I) and silver(I) cations, the molecular and crystal structures of silver(I) (triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] and silver(I) bis-(triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] are determined.

About the authors

I. A. Litvinov

Arbuzov Institute of Organic and Physical Chemistry; Tupolev National Research Technical University

Author for correspondence.
Email: litvinov@iopc.ru
Russian Federation, Kazan, Republic of Tatarstan; Kazan, Republic of Tatarstan

F. A. Karamov

Tupolev National Research Technical University

Email: litvinov@iopc.ru
Russian Federation, Kazan, Republic of Tatarstan

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