Structure of A Ni(Ii) Mixed Ligand Complex with 3-Imidazoline Nitroxide,  ISO -Propanol, and Water

G. V. Romanenko; E. Yu. Fursova; G. A. Letyagin; V. I. Ovcharenko

doi:10.1134/S002247661802018X

Structure of A Ni(Ii) Mixed Ligand Complex with 3-Imidazoline Nitroxide, ISO-Propanol, and Water

Autores: Romanenko G.V.¹, Fursova E.Y.¹, Letyagin G.A.¹^,2, Ovcharenko V.I.¹
Afiliações:
1. International Tomography Center, Siberian Branch
2. Novosibirsk State University
Edição: Volume 59, Nº 2 (2018)
Páginas: 384-387
Seção: Article
URL: https://journal-vniispk.ru/0022-4766/article/view/161883
DOI: https://doi.org/10.1134/S002247661802018X
ID: 161883

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Resumo

A mixed ligand complex of Ni(II) with 3-imidazoline nitroxide and iso-propanol [NiL₂(i-C₃H₇OH)₂] is sensitive to atmospheric moisture. It is determined that at a high humidity, the air contacts with the mother solution of the compound in iso-propanol with the precipitated [NiL₂(i-C₃H₇OH)₂] crystals leads to their spontaneous transformation into [NiL₂(H₂O)]·i-C₃H₇OH crystals whose structure is described in the present paper.