Synthesis of Nitrogen-Doped Carbon Materials
- 作者: Shlyapin D.A.1, Mishakov I.V.1, Netskina O.V.1
-
隶属关系:
- Boreskov Institute of Catalysis
- 期: 编号 6 (2025)
- 页面: 3-24
- 栏目: Articles
- URL: https://journal-vniispk.ru/0023-1177/article/view/351642
- DOI: https://doi.org/10.31857/S0023117725060015
- ID: 351642
如何引用文章
详细
The review devoted by nitrogen-doped carbon materials and strategies for their synthesis, which result in the formation of substances enriched with different forms of nitrogen — pyridine, pyrrole, quaternary (graphene-like), nitrile, amine and oxidized nitrogen. It has been shown that the predominant presence of a certain form of nitrogen in the composition of N-carbon material contributes to the manifestation of various properties that are important from a practical point of view — electrophysical, adsorption, etc. The importance of targeted regulation of the nitrogen state in N-carbon materials is also noted. Based on the analysis of approaches to N-functionalization of carbon materials considered in the literature, a fundamental scheme for obtaining materials with a predominant presence of a target form of nitrogen is proposed.
作者简介
D. Shlyapin
Boreskov Institute of Catalysis
Email: dash@catalysis.ru
630090 Nonosibirsk, Russia
I. Mishakov
Boreskov Institute of Catalysis
Email: dash@catalysis.ru
630090 Nonosibirsk, Russia
O. Netskina
Boreskov Institute of Catalysis
编辑信件的主要联系方式.
Email: dash@catalysis.ru
630090 Nonosibirsk, Russia
参考
- Chen Z., Higgins D., Yu A., et al. // Energy & Environmental Science. 2011. V. 4. № 9. P. 3167. https://doi.org/10.1039/C0EE00558D
- Gao D., Liu R., Biskupek J., et al. // Angewandte Chemie International Edition. 2019. V. 58. № 14. P. 4644. https://doi.org/10.1002/anie.201900428
- Sun P., Zhang D., He M., et al. // Electrochimica Acta. 2020. V. 337. P. 135848. https://doi.org/10.1016/j.electacta.2020.135848
- Inagaki M., Toyoda M., Soneda Y., et al. // Carbon. 2018. V. 132. P. 104. https://doi.org/10.1016/j.carbon.2018.02.024
- He L., Weniger F., Neumann H., et al. // Angewandte Chemie International Edition. 2016. V. 55. № 41. P. 12582. https://doi.org/10.1002/anie.201603198
- Zhu J., Holmen A., Chen D. // ChemCatChem. 2013. V. 5. № 2. P. 378. https://doi.org/10.1002/cctc.201200471
- Ning X., Li Y., Dong B., et al. // Journal of Catalysis. 2017. V. 348. P. 100. https://doi.org/10.1016/j.jcat.2017.02.011
- Choi E.Y., Kim D.E., Lee S.Y., et al. // Carbon. 2020. V. 166. P. 245. https://doi.org/10.1016/j.carbon.2020.05.034
- Chizari K., Deneuve A., Ersen O., et al. // ChemSusChem. 2012. V. 5. № 1. P. 102. https://doi.org/10.1002/cssc.201100276
- Wang X., Lu X., Liu B., et al. // Advanced Materials. 2014. V. 26. № 28. P. 4763. https://doi.org/10.1002/adma.201400910
- Paraknowitsch J.P., Thomas A. // Energy & Environmental Science. 2013. V. 6. № 10. P. 2839. https://doi.org/10.1039/C3EE41444B
- Lee W.J., Maiti U.N., Lee J.M., et al. // Chemical Communications. 2014. V. 50. № 52. P. 6818. https://doi.org/10.1039/C4CC00146J
- Wei D., Liu Y., Wang Y., et al. // Nano Letters. 2009. V. 9. № 5. P. 1752. https://doi.org/10.1021/nl803279t
- Chun K.Y., Lee H.S., Lee C.J. // Carbon. 2009. V. 47. № 1. P. 169. https://doi.org/10.1016/j.carbon.2008.09.047
- Hwang J.O., Park J.S., Choi D.S., et al. // ACS Nano. 2012. V. 6. № 1. P. 159. https://doi.org/10.1021/nn203176u
- Hwang S.K., Lee J.M., Kim S., et al. // Nano Letters. 2012. V. 12. № 5. P. 2217. https://doi.org/10.1021/nl204039q
- Jeong H.M., Lee J.W., Shin W.H., et al. // Nano Letters. 2011. V. 11. № 6. P. 2472. https://doi.org/10.1021/nl2009058
- Lee K.S., Lee W.J., Park N.G., et al. // Chemical Communications. 2011. V. 47. № 14. P. 4264. https://doi.org/10.1039/C1CC10471C
- Gong K., Du F., Xia Z., et al. // Science. 2009. V. 323. № 5915. P. 760. https://doi.org/10.1126/science.1168049
- Zuo S., Chen J., Liu W., et al. // Carbon. 2018. V. 129. P. 199. https://doi.org/10.1016/j.carbon.2017.12.018
- Joseph A., Thomas T. Pseudocapacitance: An introduction // Pseudocapacitors: Fundamentals to high performance energy storage devices. Cham: Springer Nature Switzerland, 2023. P. 1. https://doi.org/10.1007/978-3-031-45430-1_1
- Fleischmann S., Mitchell J.B., Wang R., et al. // Chemical Reviews. 2020. V. 120. № 14. P. 6738. https://doi.org/10.1021/acs.chemrev.0c00170
- Lee Y.H., Chang K.H., Hu C.C. // Journal of Power Sources. 2013. V. 227. P. 300. https://doi.org/10.1016/j.jpowsour.2012.11.026
- Chen L., Bai H., Huang Z., et al. // Energy & Environmental Science. 2014. V. 7. № 5. P. 1750. https://doi.org/10.1039/C4EE00002A
- Podyacheva O.Y., Ismagilov Z.R. // Catalysis Today. 2015. V. 249. P. 12. https://doi.org/10.1016/j.cattod.2014.10.033
- Pan G., Cao F., Zhang Y., et al. // Journal of Materials Science & Technology. 2020. V. 55. P. 144. https://doi.org/10.1016/j.jmst.2019.10.004
- Modi A., Bhaduri B., Verma N. // Industrial & Engineering Chemistry Research. 2015. V. 54. № 18. P. 5172. https://doi.org/10.1021/ie505016d
- Gao Y., He D., Wu L., et al. // Chemical Engineering Journal. 2021. V. 420. P. 127411. https://doi.org/10.1016/j.cej.2020.127411
- Li D., Chen W., Wu J., et al. // Journal of Materials Chemistry A. 2020. V. 8. № 47. P. 24977. https://doi.org/10.1039/D0TA07977D
- Yue L., Xia Q., Wang L., et al. // Journal of Colloid and Interface Science. 2018. V. 511. P. 259. https://doi.org/10.1016/j.jcis.2017.09.040
- Guo L., Yang J., Hu G., et al. // ACS Sustainable Chemistry & Engineering. 2016. V. 4. № 5. P. 2806. https://doi.org/10.1021/acssuschemeng.6b00327
- Rao L., Liu S., Wang L., et al. // Chemical Engineering Journal. 2019. V. 359. P. 428. https://doi.org/10.1016/j.cej.2018.11.065
- Rouzitalab Z., Maklavany D.M., Rashidi A., et al. // Journal of Environmental Chemical Engineering. 2018. V. 6. № 5. P. 6653. https://doi.org/10.1016/j.jece.2018.10.035
- Zhang Y., Liu L., Zhang P., et al. // Chemical Engineering Journal. 2019. V. 355. P. 309. https://doi.org/10.1016/j.cej.2018.08.169
- Xu J., Shi J., Cui H., et al. // Chemical Physics Letters. 2018. V. 711. P. 107. https://doi.org/10.1016/j.cplett.2018.09.038
- Chen T., Deng S., Wang B., et al. // RSC Advances. 2015. V. 5. № . 60. P. 48323. https://doi.org/10.1039/C5RA04937G
- Kim H.S., Kang M.S., Lee S., et al. // Microporous and Mesoporous Materials. 2018. V. 272. P. 92. https://doi.org/10.1016/j.micromeso.2018.06.021
- Chen J., Yang J., Hu G., et al. //ACS Sustainable Chemistry & Engineering. 2016. V. 4. № 3. P. 1439. https://doi.org/10.1021/acssuschemeng.5b01425
- Han J., Zhang L., Zhao B., et al. // Industrial Crops and Products. 2019. V. 128. P. 290. https://doi.org/10.1016/j.indcrop.2018.11.028
- Yue L., Rao L., Wang L., et al. // Industrial & Engineering Chemistry Research. 2017. V. 56. № 47. P. 14115. https://doi.org/10.1021/acs.iecr.7b02692
- Xing T., Zheng Y., Li L.H., et al. // ACS nano. 2014. V. 8. № 7. P. 6856. https://doi.org/10.1021/nn501506p
- Kondo T., Casolo S., Suzuki T., et al. // Physical Review B–Condensed Matter and Materials Physics. 2012. V. 86. № 3. P. 035436. https://doi.org/10.1103/PhysRevB.86.035436
- Guo D., Shibuya R., Akiba C., et al. // Science. 2016. V. 351. № . 6271. P. 361. https://doi.org/10.1126/science.aad0832
- Liu S., Yang H., Huang X., et al. // Advanced Functional Materials. 2018. V. 28. № 21. P. 1800499. https://doi.org/10.1002/adfm.201800499
- Li J., Tian L., Liang F., et al. // Carbon. 2019. V. 141. P. 739. https://doi.org/10.1016/j.carbon.2018.09.061
- Lim S.Y., Shen W., Gao Z. // Chemical Society Reviews. 2015. V. 44. № 1. P. 362. https://doi.org/10.1039/C4CS00269E
- Xu Q., Kuang T., Liu Y., et al. // Journal of Materials Chemistry B. 2016. V. 4. № 45. P. 7204. https://doi.org/10.1039/C6TB02131J
- Bhattacharyya S., Ehrat F., Urban P., et al. // Nature Communications. 2017. V. 8. № 1. P. 1401. https://doi.org/10.1038/s41467-017-01463-x
- Ou J., Zhang Y., Chen L., et al. // Journal of Materials Chemistry A. 2015. V. 3. № 12. P. 6534. https://doi.org/10.1039/C4TA06614F
- Gao H., Song L., Guo W., et al. // Carbon. 2012. V. 50. № 12. P. 4476. https://doi.org/10.1016/j.carbon.2012.05.026
- Li J., Ren Z., Zhou Y., et al. // Carbon. 2013. V. 62. P. 330. https://doi.org/10.1016/j.carbon.2013.05.070
- Zhu D.M., Jakovidis G., Bourgeois L. // Materials Letters. 2010. V. 64. № 8. P. 918. https://doi.org/10.1016/j.matlet.2010.01.058
- Shalagina A.E., Ismagilov Z.R., Podyacheva O.Y., et al. // Carbon. 2007. V. 45. № 9. P. 1808. https://doi.org/10.1016/j.carbon.2007.04.032
- Bulusheva L.G., Okotrub A.V., Kurenya A.G., et al. // Carbon. 2011. V. 49. № 12. P. 4013. https://doi.org/10.1016/j.carbon.2011.05.043
- Podyacheva O.Y., Shmakov A.N., Boronin A.I., et al. // Journal of Energy Chemistry. 2013. V. 22. № 2. P. 270. https://doi.org/10.1016/S2095-4956(13)60033-9
- Savilov S.V., Arkhipova E.A., Ivanov A.S., et al. // Materials Research Bulletin. 2015. V. 69. P. 7. https://doi.org/10.1016/j.materresbull.2014.12.057
- Kudashov A.G., Okotrub A.V., Yudanov N.F., et al. // Physics of the Solid State. 2002. V. 44. P. 652. https://doi.org/10.1134/1.1470550
- Guo B., Liu Q., Chen E., et al. // Nano Letters. 2010. V. 10. № 12. P. 4975. https://doi.org/10.1021/nl103079j
- Assmann J., Wolf A., Mleczko L., Felix-Karl O. Nitrogen doped carbon nanotubes with metal nanoparticles. Патент Германии WO2011080066A2, 2009.
- Trasobares S., Stephan O., Colliex C., et al. // The Journal of Chemical Physics. 2002. V. 116. № 20. P. 8966. https://doi.org/10.1063/1.1473195
- Podyacheva O.Y., Shmakov A.N., Ismagilov Z.R., et al. // Doklady Physical Chemistry. 2011. V. 439. P. 127. https://doi.org/10.1134/S0012501611070025
- Podyacheva O.Y., Shmakov A.N., Ismagilov Z.R. // Carbon. 2013. V. 52. P. 486. https://doi.org/10.1016/j.carbon.2012.09.061
- Yang J.H., Lee D.H., Yum M.H., et al. // Carbon. 2006. V. 44. № 11. P. 2219. https://doi.org/10.1016/j.carbon.2006.02.036
- Lyubutin I.S., Anosova O.A., Frolov K.V., et al. // Carbon. 2012. V. 50. № 7. P. 2628. https://doi.org/10.1016/j.carbon.2012.02.022
- Chizari K., Vena A., Laurentius L., et al. // Carbon. 2014. V. 68. P. 369. https://doi.org/10.1016/j.carbon.2013.11.013
- Arrigo R., Schuster M.E., Xie Z., et al. // ACS Catalysis. 2015. V. 5. № 5. P. 2740. https://doi.org/10.1021/acscatal.5b00094
- Mangun C.L., Benak K.R., Economy J., et al. // Carbon. 2001. V. 39. № 12. P. 1809. https://doi.org/10.1016/S0008-6223(00)00319-5
- Dong W., Li X., Jin K., et al. // Composites Part A: Applied Science and Manufacturing. 2023. V. 165. P. 107363. https://doi.org/10.1016/j.compositesa.2022.107363
- Zhang J., Chen G., Zhang Q., et al. // ACS Applied Materials & Interfaces. 2015. V. 7. № 23. P. 12760. https://doi.org/10.1021/acsami.5b01660
- Yang H.B., Miao J., Hung S.F., et al. // Science Advances. 2016. V. 2. № 4. P. e1501122. https://doi.org/10.1126/sciadv.1501122
- Zhang Z., Wang B., Zhu C., et al. // Journal of Materials Chemistry A. 2015. V. 3. № 47. P. 23990. https://doi.org/10.1039/C5TA06465A
- Wang Q., Qin B., Zhang X., et al. // Journal of Materials Chemistry A. 2018. V. 6. № 40. P. 19653. https://doi.org/10.1039/C8TA07563H
- Maksimova T.A., Mishakov I.V., Bauman Y.I., et al. // Materials. 2022. V. 15. № 22. P. 8239. https://doi.org/10.3390/ma15228239
- Brzhezinskaya M., Mishakov I.V., Bauman Y.I., et al. // Applied Surface Science. 2022. V. 590. P. 153055. https://doi.org/10.1016/j.apsusc.2022.153055
- Mishakov I.V., Bauman Y.I., Shubin Y.V., et al. // Catalysis Today. 2022. V. 388. P. 312. https://doi.org/10.1016/j.cattod.2020.06.024
- Potylitsyna A.R., Mishakov I.V., Bauman Y.I., et al. // Reaction Kinetics, Mechanisms and Catalysis. 2022. V. 135. № 3. P. 1387. https://doi.org/10.1021/cm102158w
- Ozerova A.M., Potylitsyna A.R., Bauman Y.I., et al. // Materials. 2022. V. 15. № 23. P. 8414. https://doi.org/10.3390/ma15238414
- Nishchakova A.D., Grebenkina M.A., Shlyakhova E.V., et al. // Journal of Alloys and Compounds. 2021. V. 858. P. 158259. https://doi.org/10.1016/j.jallcom.2020.158259
- Wang C., Wang F., Liu Z., et al. // Nano Energy. 2017. V. 41. P. 674. https://doi.org/10.1016/j.nanoen.2017.10.025
- Huang Y., Liao W. // Applied Surface Science. 2019. V. 495. P. 143597. https://doi.org/10.1016/j.apsusc.2019.143597
- Jiang H., Gu J., Zheng X., et al. // Energy & Environmental Science. 2019. V. 12. № 1. P. 322. https://doi.org/10.1039/C8EE03276A
- Zhu J., Xu D., Wang C., et al. // Carbon. 2017. V. 115. P. 1. https://doi.org/10.1016/j.carbon.2016.12.084
- Chen D., Wu L., Nie S., et al. // Journal of Environmental Chemical Engineering. 2021. V. 9. № 4. P. 105649. https://doi.org/10.1016/j.jece.2021.105649
- He M., Jia J., Sun Q., et al. // International Journal of Energy Research. 2021. V. 45. № 5. P. 7120. https://doi.org/10.1002/er.6297
- Lee H.J., Choi S., Oh M. // Chemical Communications. 2014. V. 50. № 34. P. 4492. https://doi.org/10.1039/C4CC00943F
- Wang Y., Liu T., Lin X., et al. // ACS Sustainable Chemistry & Engineering. 2018. V. 6. № 11. P. 13932. https://doi.org/10.1021/acssuschemeng.8b02255
- Aijaz A., Fujiwara N., Xu Q. // Journal of the American Chemical Society. 2014. V. 136. № 19. P. 6790. https://doi.org/10.1021/ja5003907
- Ge L., Yang Y., Wang L., et al. // Carbon. 2015. V. 82. P. 417. https://doi.org/10.1016/j.carbon.2014.10.085
- Soares O.S.G.P., Rocha R.P., Gonçalves A.G., et al. // Carbon. 2015. V. 91. P. 114. https://doi.org/10.1016/j.carbon.2015.04.050
- Li Y., Zhou W., Wang H., et al. // Nature Nanotechnology. 2012. V. 7. № 6. P. 394. https://doi.org/10.1038/nnano.2012.72
- Suboch A.N., Cherepanova S.V., Kibis L.S., et al. // Fullerenes, Nanotubes and Carbon Nanostructures. 2016. V. 24. № 8. P. 520. https://doi.org/10.1080/1536383X.2016.1198331
- Ning X., Yu H., Peng F., et al. // Journal of Catalysis. 2015. V. 325. P. 136. https://doi.org/10.1016/j.jcat.2015.02.010
- Kang G.S., Lee G., Cho S.Y., et al. // Applied Surface Science. 2021. V. 548. P. 149027. https://doi.org/10.1016/j.apsusc.2021.149027
- Sun M., Wu X., Deng X., et al. // Materials Letters. 2018. V. 220. P. 313. https://doi.org/10.1016/j.matlet.2018.03.050
- Liang H.W., Zhuang X., Bruller S., et al. // Nature Communications. 2014. V. 5. № 1. P. 4973. https://doi.org/10.1038/ncomms5973
- Li D., Lv C., Liu L., et al. // ACS Central Science. 2015. V. 1. № 5. P. 261. https://doi.org/10.1021/acscentsci.5b00191
- Geng D., Chen Y., Chen Y., et al. // Energy & Environmental Science. 2011. V. 4. № 3. P. 760. https://doi.org/10.1039/C0EE00326C
- Nan Y., He Y., Zhang Z., et al. // RSC Advances. 2021. V. 11. № 56. P. 35463. https://doi.org/10.1039/D1RA06458D
- Liu J., Song P., Xu W. // Carbon. 2017. V. 115. P. 763. https://doi.org/10.1016/j.carbon.2017.01.080
- Wang R., Lee J.M., Rish S.K., et al. // Fuel Processing Technology. 2022. V. 238. P. 107498. https://doi.org/10.1016/j.fuproc.2022.107498
- Lyu L., Chai H., Seong K.D., et al. // Electrochimica Acta. 2018. V. 291. P. 256. https://doi.org/10.1016/j.electacta.2018.08.111
- Wang G., Sun Y., Li D., et al. // Angewandte Chemie. 2015. V. 127. № 50. P. 15406. https://doi.org/10.1002/ange.201507735
- Silva R., Voiry D., Chhowalla M., et al. // Journal of the American Chemical Society. 2013. V. 135. № 21. P. 7823. https://doi.org/10.1021/ja402450a
- Jia N., Weng Q., Shi Y., et al. // Nano Research. 2018. V. 11. P. 1905. https://doi.org/10.1007/s12274-017-1808-8
- Liu X., Zhang J., Guo S., et al. // Journal of Materials Chemistry A. 2016. V. 4. № 4. P. 1423. https://doi.org/10.1039/C5TA09066K
- Kim G., Yang J., Nakashima N., et al. // Chemistry–A European Journal. 2017. V. 23. № 69. P. 17504. https://doi.org/10.1002/chem.201702805
- Tian Z., Huang J., Zhang X., et al. // Microporous and Mesoporous Materials. 2018. V. 257. P. 19. https://doi.org/10.1016/j.micromeso.2017.08.012
- Tong X., Chen Z., Zhuo H., et al. // Carbohydrate Polymers. 2019. V. 207. P. 764. https://doi.org/10.1016/j.carbpol.2018.12.048
- Ahn J., Song Y., Kwon J.E., et al. // Materials Science and Engineering: C. 2019. V. 102. P. 106. https://doi.org/10.1016/j.msec.2019.04.019
- Ahn J., Song Y., Kwon J.E., et al. // Data in Brief. 2019. V. 25. P. 104038. https://doi.org/10.1016/j.dib.2019.104038
- Zhou M., Lin Y., Xia H., et al. // Nano-Micro Letters. 2020. V. 12. P. 1. https://doi.org/10.1007/s40820-020-0389-3
- Ren X., Li H., Chen J., et al. // Carbon. 2017. V. 114. P. 473. https://doi.org/10.1016/j.carbon.2016.12.056
- Rao C.V., Cabrera C.R., Ishikawa Y. // The Journal of Physical Chemistry Letters. 2010. V. 1. № 18. P. 2622. https://doi.org/10.1021/jz100971v
- Tang Y., Wang X., Chen J., et al. // Energy Technology. 2020. V. 8. № 9. P. 2000361. https://doi.org/10.1002/ente.202000361
- Tang J., Salunkhe R.R., Liu J., et al. // Journal of the American Chemical Society. 2015. V. 137. № 4. P. 1572. https://doi.org/10.1021/ja511539a
- Jiang M., Cao X., Zhu D., et al. // Electrochimica Acta. 2016. V. 196. P. 699. https://doi.org/10.1016/j.electacta.2016.02.094
- Zhong H.X., Wang J., Zhang Y.W., et al. // Angewandte Chemie International Edition. 2014. V. 53. № 51. P. 14235. https://doi.org/10.1002/anie.201408990
- Shlyakhova E.V., Bulusheva L.G., Kanygin M.A., et al. // Physica status solidi (b). 2014. V. 251. № 12. P. 2607. https://doi.org/10.1002/pssb.201451228
- Bulushev D.A., Nishchakova A.D., Trubina S.V., et al. // Journal of Catalysis. 2021. V. 402. P. 264. https://doi.org/10.1016/j.jcat.2021.08.044
- Nishchakova A.D., Bulushev D.A., Trubina S.V., et al. // Nanomaterials. 2023. V. 13. № 3. P. 545. https://doi.org/10.3390/nano13030545
- Wang L., Wang L., Jin H., et al. // Catalysis Communications. 2011. V. 15. № 1. P. 78. https://doi.org/10.1016/j.catcom.2011.08.013
- Wang L.L., Zhu L.P., Bing N.C., et al. // Journal of Physics and Chemistry of Solids. 2017. V. 107. P. 125. https://doi.org/10.1016/j.jpcs.2017.03.025
- Koh K., Jeon M., Chevrier D.M., et al. // Applied Catalysis B: Environmental. 2017. V. 203. P. 820. https://doi.org/10.1016/j.apcatb.2016.10.080
- Silva R., Asefa T. // Advanced Materials. 2012. V. 24. № 14. P. 1878. https://doi.org/10.1002/adma.201104126
- Khan A., Goepel M., Colmenares J.C., et al. // ACS Sustainable Chemistry & Engineering. 2020. V. 8. № 12. P. 4708. https://doi.org/10.1021/acssuschemeng.9b07522
- Li Z., Li B., Yu C., et al. // Advanced Science. 2023. V. 10. № 7. P. 2206605. https://doi.org/10.1002/advs.202206605
- Keane M.A., Jacobs G., Patterson P.M. // Journal of Colloid and Interface Science. 2006. V. 302. № 2. P. 576. https://doi.org/10.1016/j.jcis.2006.06.057
- Mishakov I.V., Bauman Y.I., Brzhezinskaya M., et al. // Journal of Environmental Chemical Engineering. 2022. V. 10. № 3. P. 107873. https://doi.org/10.1016/j.jece.2022.107873
- Bauman Y., Kibis L., Mishakov I., et al. // Materials Science Forum. 2019. V. 950 — Material Science and Engineering Technology VII: 7th International Conference on Material Science and Engineering Technology (ICMSET 2018). P. 180. https://doi.org/10.4028/www.scientific.net/MSF. 950.180
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