Email this article Catalytic reactions of dimethyl disulfide with thiophene and benzene
- Authors: Mashkina A.V.1, Khairulina L.N.1
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Affiliations:
- Boreskov Institute of Catalysis, Siberian Branch
- Issue: Vol 57, No 1 (2016)
- Pages: 72-81
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/162383
- DOI: https://doi.org/10.1134/S0023158416010080
- ID: 162383
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Abstract
The gas-phase reaction of dimethyl disulfide with thiophene proceeds under the action of acid catalysts under atmospheric pressure at 160–350°C and a residence time of τ = 0.6–21 s to form thioalkylation and alkylation products. Dimethyl disulfide reacts with benzene to form only alkylation products. Catalysts containing both strong protic and Lewis acid sites, as well as basic sites of moderate strength, are the most active ones.
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About the authors
A. V. Mashkina
Boreskov Institute of Catalysis, Siberian Branch
Author for correspondence.
Email: amash@catalysis.ru
Russian Federation, Novosibirsk, 630090
L. N. Khairulina
Boreskov Institute of Catalysis, Siberian Branch
Email: amash@catalysis.ru
Russian Federation, Novosibirsk, 630090
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