Ring-opening metathesis polymerization (ROMP) of fullerene-containing monomers in the presence of a first-generation Grubbs catalyst
- Authors: Biglova Y.N.1, Mustafin A.G.1, Torosyan S.A.2, Biglova R.Z.1, Miftakhov M.S.2
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Affiliations:
- Bashkir State University
- Ufa Institute of Chemistry
- Issue: Vol 58, No 2 (2017)
- Pages: 111-121
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/162968
- DOI: https://doi.org/10.1134/S0023158417020021
- ID: 162968
Cite item
Abstract
New norbornene-type monomers containing covalently bound C60 fullerene have been obtained. In the presence of the 1st generation Grubbs catalyst [(PCy3)2Cl2RuCHPh] (Cy is cyclohexyl), these monomers smoothly undergo homopolymerization and copolymerization with parent fullerene-free monomers. The homopolymers are insoluble in common organic solvents, while the copolymers obtained at different molar ratios to their fullerene-free analogues are very soluble in organic solvents and can be suitable for the preparation of thin films.
About the authors
Yu. N. Biglova
Bashkir State University
Author for correspondence.
Email: bn.yulya@mail.ru
Russian Federation, Ufa, Bashkortostan, 450076
A. G. Mustafin
Bashkir State University
Email: bn.yulya@mail.ru
Russian Federation, Ufa, Bashkortostan, 450076
S. A. Torosyan
Ufa Institute of Chemistry
Email: bn.yulya@mail.ru
Russian Federation, Ufa, Bashkortostan, 450054
R. Z. Biglova
Bashkir State University
Email: bn.yulya@mail.ru
Russian Federation, Ufa, Bashkortostan, 450076
M. S. Miftakhov
Ufa Institute of Chemistry
Email: bn.yulya@mail.ru
Russian Federation, Ufa, Bashkortostan, 450054
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