Effect of the composition of the immobilized copper-containing ionic liquid on the dodecyl mercaptan oxidation kinetics


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Basic kinetic parameters of the catalytic oxidation of dodecyl mercaptan in kerosene in the presence of silica-immobilized pyridinium or imidazolium chlorocuprate complexes have been determined. The composition of the copper-containing anions and the oxidation kinetics depend on the nature of the ionic liquid and on the method of its synthesis. The compositions developed in this study are usable in the removal of hydrogen sulfide and light mercaptans from the oil stripping gas.

作者简介

I. Tarkhanova

Faculty of Chemistry

编辑信件的主要联系方式.
Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 119991

S. Verzhichinskaya

Mendeleev University of Chemical Technology of Russia

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 125047

A. Buryak

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 119071

V. Zelikman

Faculty of Chemistry

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 119991

O. Vernaya

Faculty of Chemistry

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 119991

R. Sakhabutdinov

Tatar Oil Research and Design Institute

Email: itar_msu@mail.ru
俄罗斯联邦, Bugulma, Tatarstan, 423230

R. Garifullin

Tatar Oil Research and Design Institute

Email: itar_msu@mail.ru
俄罗斯联邦, Bugulma, Tatarstan, 423230

T. Bukharkina

Mendeleev University of Chemical Technology of Russia

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 125047

L. Tyurina

Faculty of Chemistry; OOO Start-Katalizator

Email: itar_msu@mail.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

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