Photocatalytic Conversion of a FeCl3–CCl4–ROH System
- Authors: Makhmutov A.R.1
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Affiliations:
- Bashkir State University
- Issue: Vol 58, No 6 (2017)
- Pages: 695-700
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/163386
- DOI: https://doi.org/10.1134/S0023158417060052
- ID: 163386
Cite item
Abstract
The photocatalytic transformations of carbon tetrachloride and aliphatic primary alcohols in the presence of iron trichloride and a molar ratio of components FeCl3: CCl4: ROH = 1: 300: 2550 were studied. CCl4 is transformed into chloroform and hexachloroethane after exposure to a mercury lamp (250 W) to the FeCl3–CCl4–ROH system at 20°C, whereas the primary ROH alcohols are selectively oxidized into acetals (1,1-dialkoxyalkanes). The maximum conversion of CCl4 reaches 80%. The kinetics and mechanism of the photocatalytic conversion of the FeCl3–CCl4–ROH system are considered.
About the authors
A. R. Makhmutov
Bashkir State University
Author for correspondence.
Email: ainurmax@mail.ru
Russian Federation, Birsk Branch, Birsk, 452453
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