Air Oxidation of Benzoin Catalyzed by Metal-Salen Complexes


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Metal-Salen (M = Fe, Co, Ni, Cu, Zn) complexes were synthesized to catalyze the oxidation of benzoin to benzil with air as the “green” oxidizing reagent. The effects of temperature, base and solvent on M-Salen catalyzed oxidation of benzoin had been examined and optimized. The catalysis results showed that Co-Salen and Fe-Salen complexes were efficient to catalyze the oxidation reaction with yields over 80% while the catalytic activities of other three M-Salen complexes were poor. Moreover, the Co-Salen catalysis system could be reused three times with satisfied yield.

作者简介

Linjun Shao

Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process

编辑信件的主要联系方式.
Email: shaolinjun@usx.edu.cn
中国, Zhejiang Province, 312000

Qiuling Chen

Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process

Email: shaolinjun@usx.edu.cn
中国, Zhejiang Province, 312000

Chenze Qi

Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process

Email: shaolinjun@usx.edu.cn
中国, Zhejiang Province, 312000

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