Palladium–Ruthenium Catalyst for Selective Hydrogenation of Furfural to Cyclopentanol
- Авторлар: Mironenko R.M.1,2, Belskaya O.B.1,3, Lavrenov A.V.1, Likholobov V.A.1,3,4
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Мекемелер:
- Institute of Hydrocarbons Processing, Siberian Branch
- Dostoevsky Omsk State University
- Omsk State Technical University
- Omsk Scientific Center, Siberian Branch
- Шығарылым: Том 59, № 3 (2018)
- Беттер: 339-346
- Бөлім: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/163802
- DOI: https://doi.org/10.1134/S0023158418030151
- ID: 163802
Дәйексөз келтіру
Аннотация
Bimetallic Pd–Ru/C catalyst was shown to be much more active in the aqueous-phase hydrogenation of furfural (473 K, 8 MPa) in comparison with both Pd/C and Ru/C catalysts. The enhanced hydrogenation activity manifested itself as an increased yield of cyclopentanol (77%) at a complete conversion of furfural. The observed synergistic effect between palladium and ruthenium in the tested reaction can be related to changes in the electronic state and particle size of supported metals upon interaction with each other and the Pd–Ru alloy formation.
Негізгі сөздер
Авторлар туралы
R. Mironenko
Institute of Hydrocarbons Processing, Siberian Branch; Dostoevsky Omsk State University
Хат алмасуға жауапты Автор.
Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644077
O. Belskaya
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University
Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644050
A. Lavrenov
Institute of Hydrocarbons Processing, Siberian Branch
Email: mironenko@ihcp.ru
Ресей, Omsk, 644040
V. Likholobov
Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University; Omsk Scientific Center, Siberian Branch
Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644050; Omsk, 644024
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