Palladium–Ruthenium Catalyst for Selective Hydrogenation of Furfural to Cyclopentanol


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Аннотация

Bimetallic Pd–Ru/C catalyst was shown to be much more active in the aqueous-phase hydrogenation of furfural (473 K, 8 MPa) in comparison with both Pd/C and Ru/C catalysts. The enhanced hydrogenation activity manifested itself as an increased yield of cyclopentanol (77%) at a complete conversion of furfural. The observed synergistic effect between palladium and ruthenium in the tested reaction can be related to changes in the electronic state and particle size of supported metals upon interaction with each other and the Pd–Ru alloy formation.

Авторлар туралы

R. Mironenko

Institute of Hydrocarbons Processing, Siberian Branch; Dostoevsky Omsk State University

Хат алмасуға жауапты Автор.
Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644077

O. Belskaya

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University

Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644050

A. Lavrenov

Institute of Hydrocarbons Processing, Siberian Branch

Email: mironenko@ihcp.ru
Ресей, Omsk, 644040

V. Likholobov

Institute of Hydrocarbons Processing, Siberian Branch; Omsk State Technical University; Omsk Scientific Center, Siberian Branch

Email: mironenko@ihcp.ru
Ресей, Omsk, 644040; Omsk, 644050; Omsk, 644024

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