Email this article Kinetics of the Liquid-Phase Hydrochlorination of Ethanol
- Authors: Makhin M.N.1, Dmitriev G.S.1, Zanaveskin L.N.1
-
Affiliations:
- Topchiev Institute of Petrochemical Synthesis
- Issue: Vol 59, No 5 (2018)
- Pages: 553-556
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/163985
- DOI: https://doi.org/10.1134/S0023158418050099
- ID: 163985
Cite item
Open Access
Access granted
Subscription Access
Abstract
The results of a study on the kinetics of the liquid-phase hydrochlorination of ethanol with hydrogen chloride are presented. The form of the rate equation, the preexponential factor, the activation energy, and the empirical coefficients that characterize the effect of chloride anion hydration on the reaction rate of ethanol hydrochlorination were determined. The rates of hydrochlorination of monohydric alcohols and polyols were compared based on the examples of methanol, ethanol, 1,2-propylene glycol, and glycerol.
Keywords
About the authors
M. N. Makhin
Topchiev Institute of Petrochemical Synthesis
Author for correspondence.
Email: Makhin.Maxim@gmail.com
Russian Federation, Moscow, 119991
G. S. Dmitriev
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
Russian Federation, Moscow, 119991
L. N. Zanaveskin
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
Russian Federation, Moscow, 119991
Supplementary files
