Email this article Mesoporous Aluminosilicates in the Synthesis of N-Heterocyclic Compounds
- Authors: Grigor’eva N.G.1,2, Agliullin M.R.1,2, Kostyleva S.A.1, Bubennov S.V.1, Bikbaeva V.R.2, Gataulin A.R.1, Filippova N.A.1, Kutepov B.I.1,2, Narender N.3
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Affiliations:
- Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
- Ufa State Petroleuml Technological University
- CSIR-Indian Institute of Chemical Technology Uppal Road, Telangana State
- Issue: Vol 60, No 6 (2019)
- Pages: 733-743
- Section: Article
- URL: https://journal-vniispk.ru/0023-1584/article/view/164303
- DOI: https://doi.org/10.1134/S0023158419020022
- ID: 164303
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Abstract
The catalytic properties of samples of amorphous mesoporous aluminosilicate ASM with different Si/Al molar ratios (40, 80, 160) were studied in the synthesis of practically important pyridines (by the interaction of С2–С5 alcohols with formaldehyde and ammonia, cyclocondensation of acetaldehyde and propionic aldehyde with ammonia), dialkylquinolines and alkyltetrahydroquinolines (by reaction of aniline with C3, C4 aldehydes) and alkyldihydroquinolines (by interaction of aniline with ketones, acetone and acetophenone). It is found that mesoporous aluminosilicate ASM sample with a molar ratio of Si/Al = 40, which has the highest acidity among the studied samples, exhibits the highest activity and selectivity in these reactions.
About the authors
N. G. Grigor’eva
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Author for correspondence.
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075; Ufa, 450062
M. R. Agliullin
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075; Ufa, 450062
S. A. Kostyleva
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075
S. V. Bubennov
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075
V. R. Bikbaeva
Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450062
A. R. Gataulin
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075
N. A. Filippova
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075
B. I. Kutepov
Institute of Petrochemistry and Catalysis, Ufa Federal Scientific Research Center, Russian Academy of Sciences; Ufa State Petroleuml Technological University
Email: ngg-ink@mail.ru
Russian Federation, Ufa, 450075; Ufa, 450062
Nama Narender
CSIR-Indian Institute of Chemical Technology Uppal Road, Telangana State
Email: ngg-ink@mail.ru
India, Tarnaka, Hyderabad, 500 007
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