A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1

A. V. Sulimov; S. M. Danov; A. V. Ovcharova; V. R. Flid; L. G. Bruk

doi:10.1134/S0023158417060118

A Kinetic Model for the Epoxidation of Allyl Alcohol with Hydrogen Peroxide on Titanium Silicate TS-1

Autores: Sulimov A.V.¹, Danov S.M.¹, Ovcharova A.V.¹, Flid V.R.², Bruk L.G.²
Afiliações:
1. Alekseev Nizhny Novgorod State Technical University
2. Moscow Technological University
Edição: Volume 58, Nº 6 (2017)
Páginas: 673-678
Seção: Article
URL: https://journal-vniispk.ru/0023-1584/article/view/163372
DOI: https://doi.org/10.1134/S0023158417060118
ID: 163372

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Resumo

The kinetic regularities of the oxidation of allyl alcohol into glycidol in the presence of titanium silicate are studied at varied initial concentrations of the reagents, products, and temperature. The probable mechanism is used as the basis to develop a substantial kinetic model, which adequately describes the obtained experimental data.